So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Artem’ev, Alexander V.; Rogovoy, Maxim I.; Samsonenko, Denis G.; Rakhmanova, Mariana I. researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Electric Literature of C8H12Cl2Pt.They published the article 《Heterobimetallic PtII-AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence》 about this compound( cas:12080-32-9 ) in Inorganic Chemistry Communications. Keywords: platinum silver phenylpyrimidylphosphine heterobimetallic preparation thermochromic photoluminescence; crystal structure heterobimetallic silver platinum palladium phenylpyrimidylphosphine. We’ll tell you more about this compound (cas:12080-32-9).
The reaction of diphenyl(2-pyrimidyl)phosphine (L) derived complex [Pt(L)2Cl2] with AgNO3 (1:3 M ratio, resp.) results in assembly of heterobimetallic complex [AgPt(L)2(NO3)3], wherein Pt → Ag dative bond of 2.9088(2) Å is formed. This complex features thermochromic photoluminescence that appears as ∼40 nm red shift of an emission maximum upon cooling from 300 to 77 K. The related PdII/AgI complex, [AgPd(L)2(NO3)3], showing Pd → Ag dative bond of 2.9098(5) Å, also was synthesized and structurally attested.
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