So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Tosolini, Massimo; Avo, Joao; Parola, Antonio Jorge; Balducci, Gabriele; Tecilla, Paolo researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Name: Dichloro(1,5-cyclooctadiene)platinum(II).They published the article 《Sterically Encumbered 4,5-Bis(diphenylphosphino)acenaphthene Ligand and Its Ni(II), Pd(II), Pt(II), and Cu(I) Complexes》 about this compound( cas:12080-32-9 ) in European Journal of Inorganic Chemistry. Keywords: sterically encumbered diphenylphosphinoacenaphthene ligand preparation crystal mol structure complexation; nickel palladium platinum copper diphenylphosphinoacenaphthene preparation crystal mol structure. We’ll tell you more about this compound (cas:12080-32-9).
A new sterically encumbered sym. substituted 4,5-bis(diphenylphosphino)acenaphthene ligand (L) has been prepared The ligand readily forms distorted square-planar complexes with group 10 metal ions [Ni(II), Pd(II), Pt(II)] and a dimeric tetrahedral complex with Cu(I). The x-ray structures of the ligand and of the complexes show a notably short distance between the two phosphorus atoms, well below than twice the van der Waals radius of P, due to the steric requirements of the rigid acenaphthene backbone. Moreover, in the complexes a stabilizing π-π interaction between two Ph rings belonging to the two P atoms is present. The [LCuCl]2 complex is weakly fluorescent both in solution and in the solid state with higher quantum yield as a solid where it exhibits thermally-activated delayed fluorescence and phosphorescence. [LPdCl2] and [LCuCl]2 behave as chloride transporters across a liposomal phospholipid membrane with the Pd(II) complex displaying a very high activity.
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