Reference of 1-(2-Methylthiazol-4-yl)ethanone. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: 1-(2-Methylthiazol-4-yl)ethanone, is researched, Molecular C6H7NOS, CAS is 23002-78-0, about Synthesis of 4-acetylthiazole and its 2-carboxylic acid ethyl ester. Author is Sarodnick, Gerhard; Kempter, Gerhard.
4-Acetylthiazole (I, R = H) was prepared by treating BrCH2COCMe:NOH with P2S5 and HCONH2 to give 30% 4-acetylthiazole oxime which was treated with aqueous CH2O to give 65% I (R = H). I (R = Me, Ph) were also obtained by cleaving their oximes with CH2O. I (R = CO2Et) was prepared by thiolating Et oxamate, treating Et thiooxamate with BrCH2COCMe:NOH and cleaving the oxime with CH2O.
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