Related Products of 1195-58-0. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Pyridine-3,5-dicarbonitrile, is researched, Molecular C7H3N3, CAS is 1195-58-0, about Three novel zinc(II) metal-organic frameworks based on three tetrazolate ligands: synthesis, structures and photoluminescence. Author is He, Hongming; Sun, Fuxing; Zhao, Nian; Yuan, Rongrong; Zhu, Guangshan.
Three metal-organic frameworks (MOFs), [Zn(BPT)H2O] (JUC-121), [Zn5(IBT)6]·8[H2NMe2]·DMA (JUC-122) and [Zn(TPD)(H2O)2]·0.5H2O (JUC-123) (JUC = Jilin University, China), H2BPT = (5-bromo-1,3-phenylene)bis(tetrazole), H3IBT = 4,5-bis(tetrazol-5-yl)imidazole and H2TPD = 3,5-di(tetrazol-5-yl)pyridine, were obtained by the reactions of Zn(NO3)2·6H2O and three tetrazolate ligands, which were characterized by single crystal x-ray diffraction, thermal gravimetric analyses (TGA), FTIR spectra (FTIR), elemental anal. (CHN) and powder X-ray diffraction (PXRD). From the crystal structures of these complexes and the coordination modes of the ligands, the authors can see that the tetrazolate ligands have multi-connectivity abilities to obtain intriguing varieties of mol. architectures. JUC-121 displays a three-dimensional (3D) network with the point symbol (4·65)2(42·84)(64·82). JUC-122 shows a two-dimensional (2D) framework with the point symbol (243)2(24)9 and JUC-123 has a 2-dimensional bimodal (3, 3)-connected net with the point symbol (4·82). The solid-state fluorescent spectra of JUC-121, JUC-122, JUC-123 and the free ligands were measured at room temperature
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