So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Mastrocinque, Francesco; Anderson, Craig M.; Elkafas, Adel M.; Ballard, Isabel V.; Tanski, Joseph M. researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Safety of Dichloro(1,5-cyclooctadiene)platinum(II).They published the article 《Synthesis, characterization, and photophysical properties of cyclometalated N-Heterocyclic carbene Platinum(II) complexes》 about this compound( cas:12080-32-9 ) in Journal of Organometallic Chemistry. Keywords: platinum cyclometalated thienyl benzothienyl imidazolylidene benzimidazolylidene complex preparation photoluminescence; crystal structure platinum cyclometalated thienyl benzothienyl imidazolylidene benzimidazolylidene complex; mol structure platinum cyclometalated thienyl benzothienyl imidazolylidene benzimidazolylidene complex. We’ll tell you more about this compound (cas:12080-32-9).
Cyclometalated platinum complexes I (R = Me, 3-thienylmethyl; X1, X2 = H, benzo) were prepared by a two-step, one-pot procedure and characterized; the complexes showed photoluminescence at 450-550 nm. Thiophene and benzothiophene ligands containing N-heterocyclic carbene (NHC) moieties were used to synthesize five and six-membered Pt(II) metallacycles. Ligand scaffolding was synthesized using two methods. The ligands were synthesized using a coupling reaction, utilizing Cu2O as the catalyst or were synthesized using a nucleophilic substitution reaction. The ligands were then metalated by chelate-assisted C-H activation. The synthesis, characterization, reactivity, and photophys. properties of these NHC-functionalized, cyclometalated products are reported.
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