Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1787246-78-9, is researched, SMILESS is CCC1=C(C(CC)=CC=C1)N2N=C3[N+]([C@]4([C@@]([H])(OC3)CC5=C4C=CC=C5)[H])=C2.F[B-](F)(F)F, Molecular C22H24BF4N3OJournal, ACS Catalysis called Enantioselective Medium-Ring Lactone Synthesis through an NHC-Catalyzed Intramolecular Desymmetrization of Prochiral 1,3-Diols, Author is Wu, Zijun; Wang, Jian, the main research direction is enantioselective cyclization intramol desymmetrization prochiral diol heterocyclic carbene catalyst; lactone preparation.Application In Synthesis of (5aS,10bR)-2-(2,6-Diethylphenyl)-4,5a,6,10b-tetrahydro-2H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazin-11-ium tetrafluoroborate.
A highly enantioselective intramol. annulation reaction of 1,3-diols catalyzed by a triazolium N-heterocyclic carbene (NHC) precatalyst is disclosed, affording the corresponding medium-sized lactones in moderate to good yields with high enantioselectivities. It is worth noting that this compatible catalytic system was successfully applied to assemble a broad range of chiral medium-sized lactones, including ones with eight-, nine-, ten-, eleven-, and twelve-membered rings.
As far as I know, this compound(1787246-78-9)Application In Synthesis of (5aS,10bR)-2-(2,6-Diethylphenyl)-4,5a,6,10b-tetrahydro-2H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazin-11-ium tetrafluoroborate can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
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