Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 12080-32-9, is researched, SMILESS is C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-], Molecular C8H12Cl2PtJournal, Journal of Coordination Chemistry called Synthesis, reactivity and transition metal complexes of 1,1′-bis(diethynylphosphino)ferrocene, Author is Sonawane, Sachin C.; Kunchur, Harish S.; Pandey, Sameer Prasad; Balakrishna, Maravanji S., the main research direction is ferrocenyl bisphosphine preparation oxidation reaction transition metal complex; diethynylphosphinoferrocene preparation crystal mol structure reactivity transition metal complex; crystal mol structure diethynylphosphinoferrocene sulfide platinum copper complex.Formula: C8H12Cl2Pt.
The synthesis, oxidation reactions and transition metal complexes of a new ferrocenyl-bisphosphine, [Fe{C5H4P(CH)2}2] (1), are described. The reaction of bis(dichlorophosphino)ferrocene with four equivalent of ethynylmagnesium bromide resulted in the formation of 1 in 76% yield. The reaction between 1, aqueous H2O2 or elemental sulfur produced bis(oxide) and bis(sulfide) derivatives, [Fe{C5H4P(E)(CCH)2}2] (2 E = O, 3 E = S). Reaction of with [Ru(η6-p-cymene)Cl2]2 yielded a diruthenium complex [Fe{C5H4P(CCH)2}2{RuCl2(η6-p-cymene)}2] (4). Treatment of 1 with [M(COD)Cl2] (M = Pd, Pt) resulted in [Fe{C5H4P(CCH)2}2{MCl2}] (5 M = Pd, 6 M = Pt). Equimolar reactions between 1 and CuX produced binuclear complexes, [Fe{C5H4P(CCH)2}2{CuX}2] (7 X = Cl, 8 X = Br, 9 X = I).
There is still a lot of research devoted to this compound(SMILES：C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-])Formula: C8H12Cl2Pt, and with the development of science, more effects of this compound(12080-32-9) can be discovered.
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