Formula: C10H10ClNO. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 1-(4-Chlorophenyl)pyrrolidin-2-one, is researched, Molecular C10H10ClNO, CAS is 7661-33-8, about Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions. Author is Haldon, Estela; Alvarez, Eleuterio; Nicasio, M. Carmen; Perez, Pedro J..
The use of structurally well-characterized Cu(I) species as precatalysts in C-N and C-S bond forming reactions is described. Two new dinuclear Cu(I) complexes containing two isomeric ligands of bis(7-azaindolyl)methane were synthesized and fully characterized by NMR and x-ray diffraction studies. Both Cu(I) species exhibit a 1:1 Cu/L ratio and were used as precatalysts in the N-arylation of 2-pyrrolidinone and S-arylation of thiols with aryl iodides. The complexes efficiently catalyze these cross-coupling reactions, affording high yields of products under mild conditions.
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