Recently I am researching about 1,3-DIPOLAR CYCLOADDITION REACTIONS; ASYMMETRIC CYCLOADDITIONS; RHODIUM; CARBENOIDS; DIAZOESTERS; COMPLEXES; CATALYSTS, Saw an article supported by the Japan Society for the Promotion of Science (JSPS)Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [JP15K05497, JP17KT0096, JP19K05454]. Name: (4-Methoxyphenyl)methanol. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Toda, Y; Yoshida, T; Arisue, K; Fukushima, K; Esaki, H; Kikuchi, A; Suga, H. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol
Chiral Lewis acid-catalyzed asymmetric alcohol addition reactions to cyclic carbonyl ylides generated from N-(alpha-diazocarbonyl)-2-oxazolidinones featuring a dual catalytic system are reported. Construction of a chiral quaternary heteroatom-substituted carbon center was accomplished in which the unique heterobicycles were obtained in good yields with high stereoselection. The alcohol adducts were successfully converted to optically active oxazolidine-2,4-diones by hydrolysis. Mechanistic studies by DFT calculations revealed that alcohols could be activated by Lewis acids, enabling enantioselective protonation of the carbonyl ylides.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts