In 2021 CATAL SCI TECHNOL published article about GAS SHIFT REACTION; PRIMARY AMINES; NUCLEOPHILIC ALLYLATION; MOLECULAR COMPLEXITY; ALDEHYDES; RUTHENIUM; HYDROGEN; KETONES; CL; NITROARENES in [Biriukov, Klim O.; Vinogradov, Mikhail M.; Afanasyev, Oleg, I; Tsygankov, Alexey A.; Godovikova, Maria; Nelyubina, Yulia, V; Loginov, Dmitry A.; Chusov, Denis] Russian Acad Sci INEOS RAS, AN Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow, Russia; [Vasilyev, Dmitry V.] Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Egerlandstr 3, D-91058 Erlangen, Germany; [Loginov, Dmitry A.; Chusov, Denis] GV Plekhanov Russian Univ Econ, 36 Stremyanny Per, Moscow 117997, Russia in 2021, Cited 71. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks
Herein, we present the first example of Os-catalyzed efficient reductive amination under water-gas shift reaction conditions. The developed catalytic systems are formed in situ in aqueous solutions, employ as small as 0.0625 mol% osmium and are capable of delivering reductive amination products for a broad range of aliphatic and aromatic carbonyl compounds and amines. The scope of the reaction, active catalytic systems, possible limitations of the method and DFT-supported mechanistic considerations are discussed in detail in the manuscript.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts