Category: alcohols-buliding-blocks. I found the field of Chemistry very interesting. Saw the article Tandem Acceptorless Dehydrogenative Coupling-Decyanation under Nickel Catalysis published in 2021, Reprint Addresses Balaraman, E (corresponding author), Indian Inst Sci Educ & Res IISER Tirupati, Dept Chem, Tirupati 517507, Andhra Pradesh, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol.
The development of new catalytic processes based on abundantly available starting materials by cheap metals is always a fascinating task and marks an important transition in the chemical industry. Herein, a nickel-catalyzed acceptorless dehydrogenative coupling of alcohols with nitriles followed by decyanation of nitriles to access diversely substituted olefins is reported. This unprecedented C=C bond-forming methodology takes place in a tandem manner with the formation of formamide as a sole byproduct. The significant advantages of this strategy are the low-cost nickel catalyst, good functional group compatibility (ether, thioether, halo, cyano, ester, amino, N/O/S heterocycles; 43 examples), synthetic convenience, and high reaction selectivity and efficiency.
Welcome to talk about 105-13-5, If you have any questions, you can contact Midya, SP; Subaramanian, M; Babu, R; Yadav, V; Balaraman, E or send Email.. Category: alcohols-buliding-blocks
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts