An article Asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B WOS:000637925000008 published article about DIELS-ALDER REACTION; HYDROXY-O-QUINODIMETHANES; PHOTOASSISTED SYNTHESIS; ABSOLUTE STEREOCHEMISTRY; NATURAL-PRODUCT; ANALOGS THEREOF; SILYL ETHERS; XESTOQUINONE; SPONGE; HALENAQUINONE in [Lu, Xiao-Long; Qiu, Yuanyou; Yang, Baochao; Gao, Shuanhu] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663N Zhongshan Rog, Shanghai 200062, Peoples R China; [He, Haibing; Gao, Shuanhu] East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug De, 3663N Zhongshan Rd, Shanghai 200062, Peoples R China in 2021, Cited 76. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. SDS of cas: 105-13-5
The asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B was achieved in 6-7 steps using an easily accessible meso-cyclohexadienone derivative. The [6,6]-bicyclic decalin B-C ring and the all-carbon quaternary stereocenter at C-6 were prepared via a desymmetric intramolecular Michael reaction with up to 97% ee. The naphthalene diol D-E ring was constructed through a sequence of Ti(Oi-Pr)(4)-promoted photoenolization/Diels-Alder, dehydration, and aromatization reactions. This asymmetric strategy provides a scalable route to prepare target molecules and their derivatives for further biological studies.
Welcome to talk about 105-13-5, If you have any questions, you can contact Lu, XL; Qiu, YY; Yang, BC; He, HB; Gao, SH or send Email.. SDS of cas: 105-13-5
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