Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Choudhury, P; Behera, PK; Bisoyi, T; Sahu, SK; Sahu, RR; Prusty, SR; Stitgen, A; Scanlon, J; Kar, M; Rout, L in ROYAL SOC CHEMISTRY published article about in [Choudhury, Prabhupada; Behera, Pradyota Kumar; Bisoyi, Tanmayee; Sahu, Santosh Kumar; Sahu, Rashmi Ranjan; Prusty, Smruti Ranjita; Rout, Laxmidhar] Berhampur Univ, Dept Chem, Berhampur 760007, Odisha, India; [Stitgen, Abigail; Scanlon, Joseph] Ripon Coll, Dept Chem, Wisconsin Rapids, WI 54971 USA; [Sahu, Rashmi Ranjan; Kar, Manoranjan] IIT Patna, Dept Phys, Patna, Bihar, India; [Rout, Laxmidhar] Indian Inst Sci Educ & Res, Sch Chem Sci, Berhampur 760007, Odisha, India in 2021, Cited 25. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5
Herein, we report a new protocol for the dehydrogenative oxidation of aryl methanols using the cheap and commercially available catalyst CuSeO3 center dot 2H(2)O. Oxygen-bridged [Cu-O-Se] bimetallic catalysts are not only less expensive than other catalysts used for the dehydrogenative oxidation of aryl alcohols, but they are also effective under mild conditions and at low concentrations. The title reaction proceeds with a variety of aromatic and heteroaromatic methanol examples, obtaining the corresponding carbonyls in high yields. This is the first example using an oxygen-bridged copper-based bimetallic catalyst [Cu-O-Se] for dehydrogenative benzylic oxidation. Computational DFT studies reveal simultaneous H-transfer and Cu-O bond breaking, with a transition-state barrier height of 29.3 kcal mol(-1).
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