Computed Properties of C8H10O2. Authors Ruiz-Castaneda, M; Santos, L; Manzano, BR; Espino, G; Jalon, FA in WILEY-V C H VERLAG GMBH published article about in [Ruiz-Castaneda, Margarita; Santos, Lucia; Manzano, Blanca R.; Jalon, Felix A.] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim IRICA, Avda CJ Cela 10, Ciudad Real 13071, Spain; [Espino, Gustavo] Univ Burgos, Fac Ciencias, Dept Quim, Plaza Misael Banuelos S-N, Burgos 09001, Spain in 2021, Cited 107. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5
Deuterium labeling is an interesting process that leads to compounds of use in different fields. We describe the transfer hydrogenation of aldehydes and the selective C-1 deuteration of the obtained alcohols in D2O, as the only deuterium source. Different aromatic, alkylic and alpha,beta-unsaturated aldehydes were reduced in the presence of [RuCl(p-cymene)(dmbpy)]BF4, (dmbpy=4,4 ‘-dimethyl-2,2 ‘-bipyridine) as the pre-catalyst and HCO2Na/HCO2H as the hydrogen source. Moreover, furfural and glucose, were selectively reduced to the valuable alcohols, furfuryl alcohol and sorbitol. The processes were carried out in neat water or in a biphasic water/toluene system. The biphasic system allowed easy recycling, higher yields, and higher selective D incorporation (using D2O/toluene). The deuteration took place due to an efficient effective M-H/D+ exchange from D2O that allows the inversion of polarity of D+ (umpolung). DFT calculations that explain the catalytic behavior in water are also included.
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