In 2021 CHEMSUSCHEM published article about BORROWING HYDROGEN; ALPHA-ALKYLATION; AROMATIC-AMINES; BOND FORMATION; COMPLEXES; EFFICIENT; KETONES; STRATEGY; LIGANDS; IMINES in [Lan, Xiao-Bing; Ye, Zongren; Yang, Chenhui; Li, Weikang; Liu, Jiahao; Huang, Ming; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Mat Sci & Engn, PCFM Lab, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China; [Lan, Xiao-Bing] Xiangnan Univ, Sch Chem & Biol & Environm Engn, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5
The implementation of non-noble metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of non-noble metal catalysts. Herein, we report a tungsten-catalyzed N-alkylation reaction of anilines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)(4) (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible in-situ catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided.
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Reference:
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