Name: (4-Methoxyphenyl)methanol. Authors Alam, MN; Dash, SR; Mukherjee, A; Pandole, S; Marelli, UK; Vanka, K; Maity, P in AMER CHEMICAL SOC published article about in [Alam, Md Nirshad; Mukherjee, Anirban; Pandole, Satish; Marelli, Udaya Kiran; Maity, Pradip] CSIR Natl Chem Lab, Organ Chem Div, Pune 411008, Maharashtra, India; [Alam, Md Nirshad; Dash, Soumya Ranjan; Marelli, Udaya Kiran; Vanka, Kumar] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India; [Dash, Soumya Ranjan; Vanka, Kumar] CSIR Natl Chem Lab, Phys & Mat Chem Div, Pune 411008, Maharashtra, India in 2021, Cited 55. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5
A thermal O-to-C [1,3]-rearrangement of alpha-hydroxy acid derived enol ethers was achieved under mild conditions. The 2-aminothiophenol protection of carboxylic acids facilitates formation of the [1,3] precursor and its thermal rearrangement via stabilization of a radical intermediate. Experimental and theoretical evidence for dissociative radical pair formation, its captodative stability via aminothiophenol, and a unique solvent effect are presented. The aminothiophenol was deprotected from rearrangement products as well as after derivatization to useful synthons.
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