An article Ultrasmall amphiphilic zeolitic nanoreactors for the aerobic oxidation of alcohols in water WOS:000649428200001 published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; SOLID NANOPARTICLES; CATALYZED REACTIONS; PHASE INVERSION; EMULSIONS; PARTICLES; INTERFACE; CLUSTERS; SIZE in [Jing, Wendan; Li, Hui; Liu, Bolun; Wang, Runwei; Qiu, Shilun; Zhang, Zongtao] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] PetroChina, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] CNPC, Key Lab Nano Chem KLNC, Beijing 100083, Peoples R China in 2021, Cited 43. HPLC of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5
Organic reactors in a green solvent (water) is the goal of sustainable development. Green nanoreactors with excellent amphiphilicity and catalytic activity are strongly desired. Herein, a novel amphiphilic nanoreactor Pd@amZSM-5 with ultrasmall size has been successfully synthesized via a simple one-step oil bath method, subjected to the modification-etching-modification strategy and in situ reduction of Pd2+. Ultrasmall Pd@amZSM-5 nanoreactors (60 nm) with hierarchical structures showed outstanding amphiphilicity for forming Pickering emulsions with fine uniform droplets (50 mu m). Fine droplets formed short diffusion distances, which can significantly improve the catalytic activity in biphasic reactions. Moroever, the ultrasmall Pd@amZSM-5 nanoreactors demonstrated excellent catalytic activity for the selective oxidation of alcohols in water using air as the oxidant. Alkali was not present in the reaction system. The hydrophilic aminopropyl groups on the surface of the Pd@amZSM-5 nanoreactors not only changed the affinity of the zeolite surface and provided targeting points for Pd nanoparticles but also provided an alkaline environment for the selective oxidation of alcohols. The ultrasmall Pd@amZSM-5 nanoreactors presented excellent universality for aromatic alcohols (with >90% conversion and >90% selectivity) and allylic alcohols (with 100% conversion and 100% selectivity).
HPLC of Formula: C8H10O2. Welcome to talk about 105-13-5, If you have any questions, you can contact Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT or send Email.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts