An article Synthesis of Dendritic Ligand Assisted Zn/Cu Bimetallic Nanoparticles as a Highly Active Green Catalyst for Chemoselective Oxidation and Reduction Reaction WOS:000564504600011 published article about AEROBIC OXIDATION; SELECTIVE OXIDATION; ALCOHOL OXIDATION; HYDROGENATION; EFFICIENT; NITROARENES; WATER; NANOCLUSTERS; GENERATION; SUZUKI in [Islam, Sayedul; Khan, Wahab] Bangladesh Univ Engn & Technol BUET, Fac Engn, Dept Chem, Dhaka 1000, Bangladesh in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2
The dendritic ligand 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:1) 4a, 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:2) 4b, and 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (2:1) 4cbimetallic nanoparticles (NPs) were synthesized successfully by following the co-complexation route in which the desired molar ratio of Zn and Cu was confirmed by the obtained results of electron diffraction X-ray and X-ray fluorescence spectroscopy analysis. The average particle size of these NPs was detected as 15-20 nm from transmission electron microscopy investigations and agglomerate spherical surface morphology was found by scanning electron microscopy, whereas the face-centered cubic structure of these bimetallic NPs was observed by X-ray diffraction assessment. Also, the formation of the ligand was proven by IR,(HNMR)-H-1,(CNMR)-C-13, and elemental analysis. Remarkably, the chemoselective oxidation of aromatic alcohols to the corresponding aldehydes or ketones at 25 min and reduction of aromatic nitro substituents to the corresponding aniline at 20 min in aqueous medium at room temperature have been studied by the most effective catalyst Zn/Cu (2:1) 4cNPs among other molar ratios of Zn/Cu (1:1)4aand Zn/Cu (1:2) 4bNPs under atmospheric air (O-2) conditions with good to excellent yields. This green catalytic approach of Zn/Cu (2:1) 4cNPs catalytic was easily recovered by simple filtration and recycled at least five consecutive runs without a noticeable loss of its catalytic effectiveness.
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Reference:
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