Reference of 5333-42-6, The major producers of chemicals have been the Europe, Japan and China. Due to the growing call for a cleaner, greener environment, people will have to find innovative ways to maintain their relevance. Here is a compound 5333-42-6, name is 2-octyldodecan-1-ol. This compound has unique chemical properties. The synthetic route is as follows.
To a 250?mL two necked round bottom flask equipped with a stir bar, 2-octyl-1-dodecanol (20.0?g, 67.11?mmol), triphenylphosphine (21.10.g, 80.5?mmol), and imidazole (5.47?g, 80.5?mmol) in 100?mL of dichloromethane (DCM) was added at 0?C. Inert atmosphere was maintained. The solution was stirred for 15-20?min. Iodine (20.37?g, 80.5?mmol) was added to the solution with continuous stirring at 0?C. The reaction mixture was allowed to warm to room temperature over 2?h before 10?mL of sat. Na2SO3 (aq) was added. For work up firstly the organics were concentrated by evaporation, and the mixture was taken up in 200?mL of hexane washed three times with water and brine solution. The resulting mixture passed through a 3-4?cm silica gel plug, and dried over Na2SO4. The organics were concentrated by evaporation and dried under vacuum to give light yellow color oil (22.7?g, 93% yield). 1H?NMR (CDCl3, 200?MHz) deltappm: 3.01 (2H, S), 1.53 (1H, t), 1.48-1.45 (32H, s), 0.89 (t, 6H). 13C NMR (CDCl3, 200?MHz) deltappm: 13.2 (1C), 14.1(2C), 26.2 (2C), 27.7 (2C), 29.6 (4C), 29.3 (2C), 29.9 (3C), 31.9 (2C), 35.9 (1C), 39.2 (1C) Anal. Calcd for C20H41I (CHNS): C, 58.81; H, 10.12. Found: C, 58.70; H, 9.97 MALDI-TOF MS for (Calcd m/z?=?408.23) Found?=?408.97.
According to the analysis of related databases, 5333-42-6, the application of this compound in the production field has become more and more popular.
Reference:
Article; Mahale, Rajashree Y.; Dharmapurikar, Satej S.; Chini, Mrinmoy Kumar; Chemical Physics Letters; vol. 696; (2018); p. 48 – 54;,
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