Occupational methacrylate and acrylate allergy from glues was written by Aalto-Korte, Kristiina;Alanko, Kristiina;Kuuliala, Outi;Jolanki, Riitta. And the article was included in Contact Dermatitis in 2008.Formula: C10H14O5 This article mentions the following:
Background: Glues and sealants are important causes of methacrylate and acrylate allergy. Aim: This study aimed to analyze patterns of allergic patch test reactions to acrylic monomers in relation to exposure in patients sensitized from glues. Patients/Methods: We screened the patch test files at the Finnish Institute of Occupational Health from 1994 to 2006 for allergic reactions in the “Methacrylate series” and analyzed the clin. records of sensitized patients. Only patients who had handled acrylic glues at work here included. Results: 10 patients had allergic reactions to acrylic monomers and had been sensitized from glues at work. Nine of them had used anaerobic sealants, 3 cyanoacrylate-based instant adhesives, and 1 patient a bi-component instant adhesive. All the patients reached to 2-hydroxyethyl methacrylate (2-HEMA) and ethyleneglycol dimethacrylate (EGDMA); reactions to 2-hydroxypropyl methacrylate, triethyleneglycol dimethacrylate, and tetrahydrofurfuryl methacrylate were also common. The first 4 methacrylates were found in the glues used by the patients. Et cyanoacrylate (ECA) gave no reactions, but 1 patient reacted weakly to her own ECA-based glue. Conclusion: 2-HEMA and EGDMA are good screeners for contact allergy to anaerobic sealants and also detected a single case deriving from bi-component acrylic glue. In the experiment, the researchers used many compounds, for example, Diethyleneglycoldiacrylate (cas: 4074-88-8Formula: C10H14O5).
Diethyleneglycoldiacrylate (cas: 4074-88-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Formula: C10H14O5
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts