Aerobic oxidation of primary alcohols catalyzed by copper complexes of 1,10-phenanthroline-derived ligands was written by Das, Oindrila;Paine, Tapan Kanti. And the article was included in Dalton Transactions in 2012.Name: 6-Methyl-2-pyridinemethanol This article mentions the following:
Five copper complexes [(L1)2Cu(H2O)](ClO4)2 (1), [(L1)Cu(H2O)3](ClO4)2 (1a), [(L3)2Cu(H2O)](ClO4)2 (2), [(L5)2Cu(H2O)](ClO4)2 (3) and [(L6)2Cu](ClO4) (4) (where L1 = 1,10-phenanthroline, L3 = 1,10-phenanthroline-5,6-dione, L5 = 1,10-phenanthrolinefuroxan and L6 = 2,9-dimethyl-1,10-phenanthrolinefuroxan), and in situ prepared copper complexes of 2,9-dimethyl-1,10-phenanthroline (L2) or 2,9-dimethyl-1,10-phenanthrolinedione (L4) were used for aerial oxidation of primary alcs. to the corresponding aldehydes under ambient conditions. The copper catalysts have been found to catalyze a series of primary alcs. including one secondary alc. with moderate turnover numbers and selectivity towards primary alcs. Copper(ii) complexes 1 (or 1a) and 2 were found to be the better catalysts among all other systems explored in this study. A copper(ii)-superoxo species is implicated to initiate the oxidation reaction. Structural and electronic factors of 1,10-phenanthroline-based ligands affecting the catalytic results for aerial oxidation of alcs. are discussed. In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0Name: 6-Methyl-2-pyridinemethanol).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Name: 6-Methyl-2-pyridinemethanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts