Hydroxymethylpyridine containing half-sandwich complexes of Rh(III), Ir(III) or Ru(II) was written by Carmona, Daniel;Lamata, Pilar;Sanchez, Antonio;Pardo, Pilar;Rodriguez, Ricardo;Ramirez, Paola;Lahoz, Fernando J.;Garcia-Orduna, Pilar;Oro, Luis A.. And the article was included in Dalton Transactions in 2014.Recommanded Product: 6-Methyl-2-pyridinemethanol This article mentions the following:
Complexes of the formula [(畏n-ring)M(NOH){(R)-P1}][SbF6]2 ((畏n-ring)M = (畏5-C5Me5)Rh, (畏5-C5Me5)Ir, (畏6-p-MeC6H4iPr)Ru; NOH = hydroxymethylpyridine ligand; {(R)-P1} = (R)-monophos) have been prepared from the corresponding dimers [{(畏n-ring)MCl}2(渭-Cl)2] through routes involving [(畏5-C5Me5)RhCl2{(R)-P1}] or [(畏n-ring)MCl(NOH)][SbF6] intermediates. The new complexes have been characterized by anal. and spectroscopic means, including the determination of the crystal structures of [(畏5-C5Me5)IrCl2{(R)-P1}] (1b), [(畏6-p-MeC6H4iPr)RuCl(NOH-1)][SbF6] (2c), [(畏5-C5Me5)IrCl{(R)-NOH-2}][SbF6] ((R)-3b), [(畏5-C5Me5)Rh(NOH-1){(R)-P1}][SbF6]2 (4a) and [(畏6-p-MeC6H4iPr)Ru{(R)-NOH-2}{(S)-P1}][SbF6]2 ((R)-5c’) by x-ray diffractometric methods. From NMR and x-ray data, the absolute configuration of the new chiral compounds was established. In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0Recommanded Product: 6-Methyl-2-pyridinemethanol).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Recommanded Product: 6-Methyl-2-pyridinemethanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts