Polymer-Network Toughening and Highly Sensitive Mechanochromism via a Dynamic Covalent Mechanophore and a Multinetwork Strategy was written by Watabe, Takuma;Aoki, Daisuke;Otsuka, Hideyuki. And the article was included in Macromolecules (Washington, DC, United States) in 2022.Application In Synthesis of ((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) This article mentions the following:
Multinetwork (MN) elastomers exhibit outstanding mech. properties that arise from the sacrificial first network (FN). Here, we report the mech. and mechanochromic properties of an MN elastomer with a difluorenylsuccinonitrile (DFSN) moiety incorporated into the crosslinking points of its FN. DFSN is a mechanochromophore that affords stable, pink radical intermediates upon exposure to mech. stimuli. We distinctly demonstrated that the replacement of a conventional cross-linker by a weaker cross-linker does have a direct effect on the stress-strain behavior of elastomers to improve fracture toughness. The toughening mechanism of the DFSN-containing MN elastomers was revealed through a highly sensitive and quant. anal. of the mech. activated stable radicals by ESR spectroscopy. We also clarified that the MN strategy is an effective technique to achieve high activation of the mechanophores at a lower threshold strain. In the experiment, the researchers used many compounds, for example, ((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) (cas: 109-17-1Application In Synthesis of ((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)).
((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) (cas: 109-17-1) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R鈥昈鈭?. For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Application In Synthesis of ((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)
Referemce:
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