An outstanding catalyst for asymmetric transfer hydrogenation in aqueous solution and formic acid/triethylamine was written by Matharu, Daljit S.;Morris, David J.;Clarkson, Guy J.;Wills, Martin. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2006.Formula: C8H9ClO This article mentions the following:
A Rh/tetramethylcyclopentadienyl complex containing a tethered functionality has been demonstrated to give excellent results in the asym. transfer hydrogenation of ketones in both aqueous and formic acid/triethylamine media. In the experiment, the researchers used many compounds, for example, (R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9Formula: C8H9ClO).
(R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Formula: C8H9ClO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts