Synthesis of cobalt single atom catalyst by a solid-state transformation strategy for direct C-C cross-coupling of primary and secondary alcohols was written by Li, Zhijun;Chen, Yuying;Lu, Xiaowen;Li, Honghong;Leng, Leipeng;Zhang, Tinglei;Horton, J. Hugh. And the article was included in Nano Research in 2022.Name: (4-Chlorophenyl)methanol This article mentions the following:
Atomic engineering of single atom catalysts (SACs) with high-d. available active sites and optimized electronic properties can substantially boost catalytic efficacy. Herein, we report a solid-state transformation strategy to access Co SACs by introducing Co species from com. Co2O3 powders into nitrogen-doped carbon support. The catalyst exhibited excellent catalytic activity, with a turnover frequency (TOF) of 2,307 h-1 and yield of 95%, in the direct C-C cross-coupling of benzyl alc. and 1-phenylethanol (1 atm O2@80 °C) to yield chalcone. D. functional theory (DFT) calculations demonstrate the coordination environment and electronic metal-support interaction impact the catalytic pathway. In particular, a wide substrate scope and a broad functional-group tolerance of this SAC were validated, and the employment of this strategy for large-scale synthesis was also shown to be feasible. This work might shed light on the facile and scalable synthesis of highly active, selective, and stable SACs for heterogeneous catalysis. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Name: (4-Chlorophenyl)methanol).
(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Name: (4-Chlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts