Easy Scale-Up Synthesis of Mo8O26(C5H6N)4.H2O Hybrid with a Rectangular Prism Morphology and Its Application as an Efficient and Highly Recyclable Bi-functional Catalyst for Knoevenagel Condensations was written by Feghhi, Aliyeh;Malakooti, Reihaneh;Malakooti, Sadeq;Hooshmand, Nasrin. And the article was included in ChemistrySelect in 2019.Electric Literature of C7H6Cl2O This article mentions the following:
The Mo8O26(C5H6N)4.H2O hybrid with rectangular prism morphol. was synthesized via a simple wet chem. method at room temperature in water. The as-synthesized product was characterized by different methods, including X-ray diffraction (XRD), transmission electron microscopy (TEM), SEM (SEM), thermogravimetric anal. (TGA), Fourier transform IR spectroscopy (FT-IR), Raman spectroscopy, N2-adsorption/desorption and elemental anal. The Mo8O26(C5H6N)4.H2O hybrid catalyzed Knoevenagel condensation reaction as a bi-functional catalyst. Moreover, the molybdenum (VI) site in this hybrid catalyzed selective oxidation of alcs. in the presence of mol. oxygen (O2) as oxidant. The reaction of malononitrile with various aromatic aldehydes was carried out in aqueous media under mild temperature in the presence of no extra base or acid. On the other hand, the oxidation of alcs. with mol. oxygen progressed via a reusable heterogeneous system in a mild temperature The reused catalysts from both systems were identified by XRD, FT-IR, SEM and elemental anal. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Electric Literature of C7H6Cl2O).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Electric Literature of C7H6Cl2O
Referemce:
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