Oxo-Rhenium-Catalyzed Radical Addition of Benzylic Alcohols to Olefins was written by Bandari, Chandrasekhar;Nicholas, Kenneth M.. And the article was included in Journal of Organic Chemistry in 2020.Computed Properties of C7H6Cl2O This article mentions the following:
Although carbon radicals generated from a variety of alc. derivatives have proven valuable in coupling and addition reactions, the direct use of alcs. as synthetically useful radical sources is less known. In this report, benzylic alcs. are shown to be effective radical precursors for addition reactions to alkenes when treated with triphenylphosphine or piperidine with the catalyst ReIO2(PPh3)2 (I). In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Computed Properties of C7H6Cl2O).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Computed Properties of C7H6Cl2O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts