Enamine photooxidation was written by Foote, Christopher S.;Lin, John W. P.;Wong, S. Y.. And the article was included in Preprints – American Chemical Society, Division of Petroleum Chemistry in 1970.Quality Control of 1-(Dimethylamino)-2-methylpropan-2-ol This article mentions the following:
Enamines undergo photooxidative cleavage to give carbonyl compounds and amides. The reaction proceeds via an intermediate which can be reduced to an amino alc. The NMR spectra of the intermediates are not consistent with their formulation as either zwitterions or dioxetanes; they appear to be dimers or polymers of the dioxetanes. The breakdown of the intermediates (which proceeds violently in the absence bf solvent, but is smooth at temperatures below 0°) is chemiluminescent; the fluorescence of added mols. can also be induced. In the experiment, the researchers used many compounds, for example, 1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9Quality Control of 1-(Dimethylamino)-2-methylpropan-2-ol).
1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Quality Control of 1-(Dimethylamino)-2-methylpropan-2-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts