Comparative study of catalytic activity of tetrameric lanthanide-substituted polyoxotungstates [(Ln2XW10O38)4(W3O8)(OH)4(H2O)2]n- (X = SiIV, GeIV & PV and n = 26 or 25) for the oxidation of alcohols was written by Hussain, Firasat;Khan, Imran;Das, Vivek. And the article was included in Inorganica Chimica Acta in 2022.Recommanded Product: (4-Chlorophenyl)methanol This article mentions the following:
The catalytic activity of tetrameric lanthanide-substituted phospho, germano and silicotungstate with the formula [(Ln2XW10O38)4(W3O8)(OH)4(H2O)2]n- (X = SiIV, GeIV & PV and n = 26 or 25) {Ln8X4W40} (X = SiIV, GeIV or PV) has been investigated for the oxidation of alc. derivatives in homogeneous medium. The comparative study shows that the lanthanide-substituted phosphotungstates possesses better catalytic activity over the silico and germanotungstate analogs. The reaction was carried out in eco-friendly solvent (water) in presence of green oxidant (H2O2). The recovered catalysts were characterized by FT-IR spectroscopy and powder X-ray diffraction (PXRD). The catalysts are stable and can be recovered even after five consecutive cycles of reaction with only a slight loss in its catalytic activity. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Recommanded Product: (4-Chlorophenyl)methanol).
(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: (4-Chlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts