Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions was written by Harinath, Adimulam;Bhattacharjee, Jayeeta;Panda, Tarun K.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Computed Properties of C7H6Cl2O This article mentions the following:
A facile protocol for the deoxygenative hydroboration of aliphatic and aryl carboxylic acids afforded corresponding primary alcs. under solvent-free and catalyst-free conditions was reported. The reaction proceeded under ambient temperature exhibited good tolerance towards various functional groups and generates quant. yields. The plausible mechanism involved the formation of Lewis acid-base adducts as well as the liberation of hydrogen gas. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Computed Properties of C7H6Cl2O).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Computed Properties of C7H6Cl2O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts