Zhang, Yahui published the artcileSelective electrocatalytic hydroboration of aryl alkenes, Application In Synthesis of 608534-44-7, the publication is Green Chemistry (2021), 23(4), 1691-1699, database is CAplus.
Organoboron compounds are powerful precursors of value-added organic compounds in synthetic chem., and transition metal-catalyzed borylation has always been dominant. To avoid toxic reagents and costs associated with metal catalysts, simpler, more economical and effective approaches for delivering organoborons are highly desirable. Here, without the use of any metal catalysts, a CH3CN-involved electrochem. borylation reaction is reported with alkenes and HBpin as substrates. The site-selectivity is realized to achieve mono- or di-functional borylation of an unsaturated bond by regulating the proportion of HBpin. In addition, the success of gram-scale experiments and versatile conversions confirms the potential applications of this strategy in industrial synthesis. The vital auxiliary role of N,N-diisopropylethylamine (DIEA) in the process of acetonitrile electrolysis is disclosed in the mechanism study. The proposed new strategy provides a generic platform for the discovery of addnl. challenging electrochem. systems for hydrogenation reactions.
Green Chemistry published new progress about 608534-44-7. 608534-44-7 belongs to alcohols-buliding-blocks, auxiliary class Other Aromatic,Boronic acid and ester,Boronate Esters,Boronic Acids,Boronic acid and ester, name is 2-(2,3-Dihydro-1H-inden-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, and the molecular formula is C12H14O, Application In Synthesis of 608534-44-7.
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