Wang, Ting published the artcileSelective hydroconversion of 2-methylfuran to pentanols on MWNT-supported Pt catalyst at ambient temperature, Application In Synthesis of 111-29-5, the publication is Rare Metals (Beijing, China) (2022), 41(3), 889-900, database is CAplus.
The selective hydrogenolysis of C-O bond in furfural and its derivatives provides a sustainable route for transforming biomass-derived feedstocks into valued chems. Currently, the development of efficient catalysts which can effectively cleavage C-O bond under mild conditions remains a critical challenge. The present work reports Pt catalysts supported on multi-walled carbon nanotubes (MWNT) which are active in 2-methylfuran (2-MF) hydrogenolysis to form pentanols in liquid phase under mild conditions. The impact of various catalyst supports, active metals and reaction conditions in terms of metal loadings, solvent, time, pressure, etc. were explored. The 5 wt% Pt/MWNT catalyst demonstrated an excellent activity and selectivity with 100% 2-MF conversion and 53% pentanols (POLs) yield under 1 MPa H2 at an exceptional low temperature of 25°C. The reaction mechanism was studied combing both the reactivity tests and characterization results, and it is found that the better catalytic performances of Pt/MWNT were correlated closely to the size of Pt nanoparticles and their interactions with the underlying MWNT support. Accordingly, a reaction pathway involving the adsorption of 2-MF parallel to the Pt nanoparticles and its subsequently selective C-O hydrogenolysis was proposed. This work showcases a promising catalyst for room-temperature biofuel production
Rare Metals (Beijing, China) published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C13H10N2S, Application In Synthesis of 111-29-5.
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