Pedrick, E. A. published the artcileReductive silylation of a uranyl dibenzoylmethanate complex: an example of controlled uranyl oxo ligand cleavage, Application of Triethylsilanol, the publication is Chemical Science (2014), 5(8), 3204-3213, database is CAplus.
Reaction of UO2(dbm)2(THF) (dbm = OC(Ph)CHC(Ph)O) with 1 equiv of R3SiH (R = Ph, Et), in the presence of B(C6F5)3, gave U(OB{C6F5}3)(OSiR3)(dbm)2(THF) (R = Ph, 1; Et, 2), which were isolated as red-orange crystalline solids in good yields. The addition of 1 equiv of H(dbm) to 2 results in protonation of the -OSiEt3 ligand and formation of U(OB{C6F5}3)(dbm)3 (4) in 33% yield, along with formation of HOSiEt3. Furthermore, addition of HOSiEt3 and 1 equiv of THF to 4, results in the formation 2, revealing that this process is reversible. The two-step conversion of UO2(dbm)2(THF) to 4 represents a rare example of controlled uranyl oxo ligand cleavage at ambient temperature and pressure. Comparison of diffraction and d. functional theory data for 4 suggests the inverse trans influence (ITI), with a very shallow potential energy well for distortion along the trans U-O bond.
Chemical Science published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Application of Triethylsilanol.
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