Pein, Wesley L. published the artcileNickel-Catalyzed Ipso-Borylation of Silyloxyarenes via C-O Bond Activation, Application In Synthesis of 27292-49-5, the publication is Organic Letters (2021), 23(12), 4588-4592, database is CAplus and MEDLINE.
The conversion of silyloxyarenes to boronic acid pinacol esters via Ni catalysis is described. In contrast to other borylation protocols of inert C-O bonds, the method is competent in activating the C-O bond of silyloxyarenes in isolated aromatic systems lacking a directing group. The catalytic functionalization of benzyl silyl ethers was also achieved under these conditions. Sequential cross-coupling reactions were achieved by leveraging the orthogonal reactivity of silyloxyarenes, which could then be functionalized subsequently.
Organic Letters published new progress about 27292-49-5. 27292-49-5 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Benzene,Phenol, name is 3-Morpholinophenol, and the molecular formula is C10H13NO2, Application In Synthesis of 27292-49-5.
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