Toelle, Nina published the artcileLight-mediated total synthesis of 17-deoxyprovidencin, COA of Formula: C3H6O2, the publication is Angewandte Chemie, International Edition (2014), 53(15), 3859-3862, database is CAplus and MEDLINE.
An asym. synthesis of the diterpenoid 17-deoxyprovidencin I is described. Key steps include an aldol addition, a base-catalyzed Wipf-type furan formation, a Z-selective ring-closing metathesis for macrocyclization, a photochem. E/Z isomerization to a highly strained and conformationally restricted ring system, and the stereoselective formation of two epoxides on the ring.
Angewandte Chemie, International Edition published new progress about 57044-25-4. 57044-25-4 belongs to alcohols-buliding-blocks, auxiliary class Epoxides,Chiral,Aliphatic hydrocarbon chain,Alcohol, name is (R)-Oxiran-2-ylmethanol, and the molecular formula is C8H7ClO3, COA of Formula: C3H6O2.
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