Ou, Zhi Rong’s team published research in Macromolecules (Washington, DC, United States) in 2022-01-11 | CAS: 7575-23-7

Macromolecules (Washington, DC, United States) published new progress about Binding energy. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, Product Details of C17H28O8S4.

Ou, Zhi Rong published the artcileControllable Depolymerization and Recovery of Interlocked Covalent Adaptable Networks via Cascading Reactions of the Built-In Reversible Bonds, Product Details of C17H28O8S4, the main research area is controllable depolymerization interlocked covalent adaptable network.

A novel strategy for controllable depolymerization and recovery of polymer blends is proposed. The core advance lies in the application of reversible boronic ester bonds and imine bonds, which possess the abilities of correlative scission and rebuilding. Accordingly, reversibly interlocked polymer networks (RILNs) are prepared from two preformed crosslinked polymers, which resp. carry the two reversible bonds. By taking advantage of the intimate packing of the macromols. from the two networks in the RILNs, the cascading effect between boronic ester bonds and imine bonds is enabled. When the DMF swollen RILNs are triggered by a little water, the boronic ester bonds in one component network are decomposed, affording boronic acid, which subsequently catalyzes the cleavage of the adjacent imine bonds in the other component network. Meanwhile, scission of the imine bonds also promotes decomposition of the boronic ester bonds as well. The cascading processes can be reversed via dehydration-induced reformation of boronic ester bonds. Hence, RILNs are allowed to be depolymerized in a controlled manner and then recovered by removing the solvent and water.

Macromolecules (Washington, DC, United States) published new progress about Binding energy. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, Product Details of C17H28O8S4.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts