Khedri, Zohrab published the artcileKirkwood-Buff integrals and structure factor for binary mixtures of ionic liquid with 1-alkanol, Safety of n-Octanol, the main research area is alkanol Kirkwood Buff integral binary mixture ionic liquid.
In this paper, we have tried to describe the factors affecting mol. interactions and structure of binary systems including 1-Hexyl-3-methylimidazolium Nitrate ([Hmim][NO3]) and 1-alkanol (1-hexanol, up to 1-decanol) using Kirkwood-Buff (KB) integrals and structure factor. Obtained results indicate that unlike mols. tend to form favorable interactions via forming hydrogen bonds or dipolar interactions and stay alongside, while an increase in the carbon chain of 1-alkanols reduces the strength of bonds and tendency of the unlike mols. to stay together. Moreover, the structure of mixtures was studied using the concentration-concentration structure factor, SCC(0). Results from the application of this parameter show that in all binary mixtures, heterocoordination is predominant, ordering occurs in solutions and fluctuations are less than random orientation. In addition, the chem. short-range order parameter α’, which is an important function to understand the complex formation and phase segregation in the liquid mixtures, was calculated and discussed for mentioned mixtures For current binary mixtures, exptl. data and theor. investigations are novel and reported for the first time.
Journal of Molecular Liquids published new progress about Binary mixtures. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Safety of n-Octanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts