Eitzinger, Andreas published the artcileEnantioselective Bifunctional Ammonium Salt-Catalyzed Syntheses of 3-CF3S-, 3-RS-, and 3-F-Substituted Isoindolinones, COA of Formula: C8H10S, the publication is Advanced Synthesis & Catalysis (2021), 363(7), 1955-1962, database is CAplus and MEDLINE.
Herein, ammonium salt-catalyzed synthesis of chiral 3,3-disubstituted isoindolinones, e.g., I bearing a heteroatom functionality in the 3-position was reported. A broad variety of differently substituted CF3S- and RS-derivatives were obtained with often high enantioselectivities when using Maruoka’s bifunctional chiral ammonium salt catalyst. In addition, a first proof-of-concept for the racemic synthesis of the analogous F-containing products was obtained as well, giving access to one of the rare examples of a fairly stable α-F-α-amino acid derivative
Advanced Synthesis & Catalysis published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C8H10S, COA of Formula: C8H10S.
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