Tolnai, Gergely L. published the artcileEfficient O-Functionalization of Carbohydrates with Electrophilic Reagents, Computed Properties of 20880-92-6, the publication is Angewandte Chemie, International Edition (2016), 55(37), 11226-11230, database is CAplus and MEDLINE.
Novel methodol. for O-functionalization of carbohydrate derivatives has been established using bench-stable and easily prepared iodonium(III) reagents. Both electron-withdrawing and electron-donating aryl groups were introduced under ambient conditions and without precautions to exclude air or moisture. Furthermore, the approach was extended both to full arylation of cyclodextrin, and to trifluoroethylation of carbohydrate derivatives This is the first general approach to introduce traditionally non-electrophilic groups into any of the OH groups around the sugar backbone. The methodol. will be useful both in synthetic organic chem. and biochem., as important functional groups can be incorporated under simple and robust reaction conditions in a fast and efficient manner.
Angewandte Chemie, International Edition published new progress about 20880-92-6. 20880-92-6 belongs to alcohols-buliding-blocks, auxiliary class Other Aliphatic Heterocyclic,Chiral,Alcohol, name is ((3aS,5aR,8aR,8bS)-2,2,7,7-Tetramethyltetrahydro-3aH-bis([1,3]dioxolo)[4,5-b:4′,5′-d]pyran-3a-yl)methanol, and the molecular formula is C13H10O2, Computed Properties of 20880-92-6.
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