Bagherzadeh, Sharareh published the artcileCatalyst Control of Selectivity in CO2 Reduction Using a Tunable Heterobimetallic Effect, COA of Formula: C6H13BO3, the publication is Journal of the American Chemical Society (2015), 137(34), 10898-10901, database is CAplus and MEDLINE.
A tunable bimetallic effect on product selectivity in catalytic CO2 reduction was identified using N-heterocyclic carbene-ligated Cu complexes. While the monometallic Cu-only system catalyzes hydroboration of CO2 with pinacolborane to produce formate exclusively, introducing a bimetallic effect with analogous Cu-Fe, Cu-W, and Cu-Mo catalysts produces mixtures of formate and CO. Within a series of isosteric catalysts, the selectivity of CO vs. formate was controlled by tuning the electronic nature of the Cu/M pairing, with high selectivity for CO being achieved using a Cu-Mo catalyst.
Journal of the American Chemical Society published new progress about 25240-59-9. 25240-59-9 belongs to alcohols-buliding-blocks, auxiliary class Boronic acid and ester,Boronic Acids,Boronate Esters, name is 4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-ol, and the molecular formula is C6H13BO3, COA of Formula: C6H13BO3.
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