The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 100-86-7, Name is 2-Methyl-1-phenyl-2-propanol, SMILES is CC(O)(C)CC1=CC=CC=C1, in an article , author is Bhunia, Anup, once mentioned of 100-86-7, Name: 2-Methyl-1-phenyl-2-propanol.
Fe-Catalyzed Anaerobic Mukaiyama-Type Hydration of Alkenes using Nitroarenes
Hydration of alkenes using first row transition metals (Fe, Co, Mn) under oxygen atmosphere (Mukaiyama-type hydration) is highly practical for alkene functionalization in complex synthesis. Different hydration protocols have been developed, however, control of the stereoselectivity remains a challenge. Herein, highly diastereoselective Fe-catalyzed anaerobic Markovnikov-selective hydration of alkenes using nitroarenes as oxygenation reagents is reported. The nitro moiety is not well explored in radical chemistry and nitroarenes are known to suppress free radical processes. Our findings show the potential of cheap nitroarenes as oxygen donors in radical transformations. Secondary and tertiary alcohols were prepared with excellent Markovnikov-selectivity. The method features large functional group tolerance and is also applicable for late-stage chemical functionalization. The anaerobic protocol outperforms existing hydration methodology in terms of reaction efficiency and selectivity.
Interested yet? Read on for other articles about 100-86-7, you can contact me at any time and look forward to more communication. Name: 2-Methyl-1-phenyl-2-propanol.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts