Gajare, Vikas S. published the artcileA concise stereoselective synthesis of (+)-1-deoxy-6-epi-castanospermine, SDS of cas: 57044-25-4, the publication is Tetrahedron Letters (2016), 57(13), 1486-1488, database is CAplus.
A concise stereoselective synthesis of (+)-1-deoxy-6-epi-castanospermine has been developed through stereoselective approach from the chiral precursor R-glycidol. The key steps in the synthesis involve Grignard reaction through Weinreb amide, followed by Sharpless dihydroxylation and stereoselective reduction of imine assigned the required stereochem. feature of indolizidine azasugar (+)-1-deoxy-6-epi-castanospermine.
Tetrahedron Letters published new progress about 57044-25-4. 57044-25-4 belongs to alcohols-buliding-blocks, auxiliary class Epoxides,Chiral,Aliphatic hydrocarbon chain,Alcohol, name is (R)-Oxiran-2-ylmethanol, and the molecular formula is C3H6O2, SDS of cas: 57044-25-4.
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