Motokura, Ken published the artcileCopper-Catalyzed Formic Acid Synthesis from CO2 with Hydrosilanes and H2O, Computed Properties of 597-52-4, the publication is Organic Letters (2012), 14(10), 2642-2645, database is CAplus and MEDLINE.
A copper-catalyzed formic acid synthesis from CO2 with hydrosilanes has been accomplished. The Cu(OAc)2·H2O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO2. The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR anal. and isotopic experiments
Organic Letters published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Computed Properties of 597-52-4.
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