Zhang, Jingwu published the artcileReaction-activated palladium catalyst for dehydrogenation of substituted cyclohexanones to phenols and H2 without oxidants and hydrogen acceptors, Computed Properties of 27292-49-5, the publication is Chemical Science (2015), 6(8), 4674-4680, database is CAplus and MEDLINE.
It was widely believed that the dehydrogenation of organic compounds was a thermodynamically unfavorable process, and thus required stoichiometric oxidants such as dioxygen and metal oxides or sacrificial hydrogen acceptors to remove the hydrogen from the reaction mixture to drive the equilibrium towards the products. A previously unappreciated combination of common com. Pd/C and H2 which dehydrogenated a wide range of substituted cyclohexanones and 2-cyclohexenones to their corresponding phenols with high isolated yields, with H2 as the only byproduct was reported. The reaction requires no oxidants or hydrogen acceptors because instead of removing the generated hydrogen with oxidants or hydrogen acceptors, it was used as a cocatalyst to help power the reaction. The method for phenol synthesis manifested a high atom economy, and was inherently devoid of the complications normally associated with oxidative dehydrogenations.
Chemical Science published new progress about 27292-49-5. 27292-49-5 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Benzene,Phenol, name is 3-Morpholinophenol, and the molecular formula is C38H24F4O4P2, Computed Properties of 27292-49-5.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts