Gazizov, M. B. published the artcileSynthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles, Product Details of C8H19NO2, the publication is Russian Chemical Bulletin (2016), 65(1), 191-194, database is CAplus.
4-(Dibromomethyl)benzenecarbaldehyde (4-Br2CHC6H4CHO, I) was prepared chemoselectively by debromination of 1,4-bis(dibromomethylbenzene) with tri-Me phosphate; reaction with primary amines RNH2 [R = i-Pr, 4-MeOC6H4, (EtO)2CHCH2, (EtO)2CH2CH2CH2] yielded benzaldimines 4-Br2CHC6H4CH:NR [R = i-Pr, 4-MeOC6H4, (EtO)2CHCH2, (EtO)2CH2CH2CH2], while reaction with tri-Me and tri-Et orthoformates in the presence of H2SO4 yielded the acetals 4-Br2CHC6H4CH(OR1)2 (R1 = Me, Et).
Russian Chemical Bulletin published new progress about 6346-09-4. 6346-09-4 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Ether, name is 4,4-Diethoxybutan-1-amine, and the molecular formula is C8H19NO2, Product Details of C8H19NO2.
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