Bellotti, Peter published the artcileCatalytic defluorinative ketyl-olefin coupling by halogen-atom transfer, COA of Formula: C5H12O2, the publication is Chemical Science (2022), 13(26), 7855-7862, database is CAplus and MEDLINE.
A new approach to achieve catalytic ketyl-olefin coupling reactions by a halogen-atom transfer mechanism provides innovative and efficient access to various gem-difluorohomoallylic alcs. 4-OCH3C6H4C(=C(F)2)CH2C(OC(O)C6H5)R [R = H, n-pentyl, cyclohexyl, 2-(4-fluorophenyl)ethyl, etc.] under mild conditions with broad substrate scope. Preliminary mechanistic exptl. and computational studies demonstrate that this radical-to-polar crossover transformation could be achieved by sequentially orchestrated Lewis acid activation, halogen-atom transfer, radical addition, single-electron reduction and β-fluoro elimination.
Chemical Science published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C5H12O2, COA of Formula: C5H12O2.
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