Zhao, Ling’s team published research in Journal of Organic Chemistry in 87 | CAS: 111-29-5

Journal of Organic Chemistry published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C8H5F3N4, Safety of Pentane-1,5-diol.

Zhao, Ling published the artcileAcceptorless Dehydrogenative Cross-Coupling of Primary Alcohols Catalyzed by an N-Heterocyclic Carbene-Nitrogen-Phosphine Chelated Ruthenium(II) Complex, Safety of Pentane-1,5-diol, the publication is Journal of Organic Chemistry (2022), 87(7), 4550-4559, database is CAplus and MEDLINE.

The acceptorless dehydrogenative cross-coupling of primary alcs. to form cross-esters with the liberation of H2 gas was enabled using a [RuCl(η6-C6H6)(κ2-CNP)][PF6]Cl complex as the catalyst. This sustainable protocol was applicable to a broad range of primary alcs., particularly for the sterically demanding ones, featuring good functional group tolerance and high selectivity. The good catalytic performance can be attributed to the nitrogen-phosphine-functionalized N-heterocyclic carbene (CNP) ligand, which adopted a facial coordination mode as well as the facile dissociation of coordinated benzene.

Journal of Organic Chemistry published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C8H5F3N4, Safety of Pentane-1,5-diol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts