Kurogome, Yuji published the artcileSynthesis of Decytospolide A, B and Their C-3 Epimers Using Stereoselective Oxypalladation, Quality Control of 57044-25-4, the publication is Synthesis (2016), 48(5), 765-771, database is CAplus.
Stereoselective synthesis of decytospolide A and B (I and II, resp.) and their C-3 epimers, which have a 2,6-cis-tetrahydropyran ring, has been achieved in high stereoselectivity and yield. The oxypalladation of single diastereomers of 6-(benzyloxy)-7-hydroxydodec-2-enyl 2-naphthoates was optimized to give products with a 2,6-cis-tetrahydropyran ring with high diastereoselectivity and yield.
Synthesis published new progress about 57044-25-4. 57044-25-4 belongs to alcohols-buliding-blocks, auxiliary class Epoxides,Chiral,Aliphatic hydrocarbon chain,Alcohol, name is (R)-Oxiran-2-ylmethanol, and the molecular formula is C3H6O2, Quality Control of 57044-25-4.
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