Ghosh, Kousik published the artcileA triple alkoxo bridged dinuclear cobalt(III) complex mimicking phosphatase and showing ability to degrade organic dye contaminants by photocatalysis, COA of Formula: C4H11NO, the publication is Journal of Organometallic Chemistry (2019), 52-64, database is CAplus.
A dinuclear Co(III) complex, [(N3)L1CoIIIL2CoIIIL1] (1), was synthesized and characterized {H2L1 = 2-((1-hydroxybutan-2-ylimino)methyl)-4-bromophenol and HL2 = 2-amino-1-butanol}. Single crystal x-ray diffraction anal. confirmed its structure. Extended supra-mol. architectures were generated in the complex through weak noncovalent interactions. The energetic features of significant supramol. interactions were studied using DFT calculation and further corroborated with NCI plot index computational tool. The complex was found to mimic the role of phosphatase enzyme efficiently by transforming 4-nitrophenylphosphate to 4-nitrophenolate at room temperature The reaction follows Michaelis-Menten enzymic reaction kinetics with turnover numbers of ∼1.4 s-1 in aqueous DMF (98% DMF, volume/volume) medium. The complex also acts as an efficient photocatalyst for degradation of organic pollutants. Methylene blue (MB), a widely used dye in various industries, was selected as a model pollutant in aqueous media to evaluate the photocatalytic effectiveness of the complex.
Journal of Organometallic Chemistry published new progress about 96-20-8. 96-20-8 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Alcohol, name is 2-Aminobutan-1-ol, and the molecular formula is C4H11NO, COA of Formula: C4H11NO.
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