Xu, Shiyang published the artcileRh(I)-Catalyzed Coupling of Azides with Boronic Acids Under Neutral Conditions, Category: alcohols-buliding-blocks, the publication is Organic Letters (2022), 24(30), 5546-5551, database is CAplus and MEDLINE.
A neutral amination reaction using azides RN3 (R = Ph, 4-nitrophenyl, 4-bromophenyl, etc.) as the nitrogen source and arylboronic acids ArB(OH)2 (Ar = 4-cyanobutyl, cyclooctyl, Ph, etc.) with a rhodium(I) catalyst to afford alkyl-aryl and aryl-aryl secondary amines RNHAr was presented. Natural products and pharmaceutical derivatives were applied, and gram-scale reactions were performed, which demonstrated the utility. Mechanistic experiments and DFT calculations suggested that the reaction involves a metal-nitrene intermediate.
Organic Letters published new progress about 622-40-2. 622-40-2 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Alcohol, name is 2-Morpholinoethanol, and the molecular formula is C4H8Cl2S2, Category: alcohols-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts